Consider the following reaction.
4 A + B + 4 C 4 D + E
The following data was collected on the reaction.
| Trial | [A]0 | [B]0 | [C]0 | Rate (M/s) |
| 1 | 0.52 | 0.52 | 0.52 | 5.394 |
| 2 | 1.04 | 0.52 | 0.52 | 10.788 |
| 3 | 0.52 | 1.04 | 0.52 | 10.788 |
| 4 | 0.52 | 0.52 | 1.04 | 5.394 |
Two mechanisms are proposed:
Mechanism 1:
| A + B | D + Y | |
| Y + C | X | |
| X + A + C | D + Z | |
| Z + A | E |
Mechanism 2:
| A + C | D + Y | |
| Y + B + C | X + D | |
| X + A + C | E |
Which mechanism best fits the data?
Which is most likely the rate-determining step?