Consider the following reaction.
3 A + B + 4 C 3 D + E
The following data was collected on the reaction.
Trial | [A]0 | [B]0 | [C]0 | Rate (M/s) |
1 | 0.57 | 0.59 | 0.57 | 4.344 |
2 | 1.14 | 0.59 | 0.57 | 4.344 |
3 | 0.57 | 1.18 | 0.57 | 8.688 |
4 | 0.57 | 0.59 | 1.14 | 8.688 |
Two mechanisms are proposed:
Mechanism 1:
A + B | D + Y | |
Y + C | X | |
X + A + C | D + Z | |
Z + A | E |
Mechanism 2:
A + C | D + Y | |
Y + B + C | X + D | |
X + A + C | E |
Which mechanism best fits the data?
Which is most likely the rate-determining step?